What we call "concrete" has been used in some form since ancient times.
"Artificial stone" pavement was patented in 1871, although we call it "concrete" now.
See Schillinger Artificial Stone 1870 Patent photo below taken on South Van Ness in San Francisco.
The word "concrete" was not associated with building materials until about 1830 when
Joseph Aspdin of England invented the binder in what we now call concrete--that binder called "cement".
Although, the word "cement" was used until the turn of the
century for what we now know as concrete.